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AAR " 6$R,$D 0 4_(4.4a)T(4.4b)y:N5ug5uRveyre zfB      H  0޽h ? ̙3333___PPT10+(D' = @B D' = @BA?%,( < +O%,( < +D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*Dn' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*Dn' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<* D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<* Dn' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*$D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*$D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*"%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*"D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*"++0+  ++0+  ++0+"  ++  Z(  r  S \`0     0܎,$ 0 @ (Weyre z_-N `$ n :NJSS^-N_1Yv5uP[pe|!b f 3b ff f(      0ܔ ` ,$ 0 pc$~mSO0~VSO Nh:y(W_-N0 f   6H,$ 0 <a$a['l]bb[؏]vNJSS^-NTir(vSf[ϑpe:Ncpe nfffff@     z ?   ? ,$D 0  0? ,$ 0 <b$5ugS^-Ngir(/flSO R(uv[RS p/p h:y0 ffff ff(     n3 # 5q8,$D 02   H >?" n3zB   < D>?" 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AAH  0޽h ? ̙3333{___PPT10[+8K D' = @B DR' = @BA?%,( < +O%,( < +D' =%(D?' =%(D' =A@BBBB0B@B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' K=+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' K=+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*Dn' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*Dn' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<* D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<* ++0+  ++0+  ++0+  +9)  5-0 (  @  0?.,$D 0 DO4.2 {OH-Sm^:N0.100moldm-3e 'lv5ug5uR (O2/OH-)0]wp(O2)=101.325kPa T=298.15K0 Pb`bbj,bjb J b bjbj,bbbbbj bb bh           2  6(O{B,$D 0 *NDU_10-NSg_'lvhQ5ug5uR <bbc hl 1f S,$D 0D@ 1f 1f  <T f,$D 0 ( (O2/OH -)=0.401V b Jbjbj,b b     <\1 ,$D 0 0DO2(g)+ 2H2O +4e- 4OH -(aq) #bjbjbj bj,b&   ~  C A? ,$D 0  n3  # )e ,$D 02   H >?" n3zB   < D>?" 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AA  S A O??8 jR8 O$D 0  6Tr P7,$D 0 } = 0.460V 6 Bb B  H  0޽h ? ̙3333___PPT10+ΆD' = @B D' = @BA?%,( < +O%,( < +D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*Dn' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*Dn' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<* D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<* +p+0+  ++0+  +$  V N  (  r  S <\`0   z V  y,$D 0f  64V,$D 0  傊b5ugS^_Qb O2+H2O+2e-=2OH- ,SNǏ{NNf09hnc5ugS^_ dke5ug5uRv{_:N: L@ bjbjbjbjbj$!bc(  &   c $A M?? Z 8 M$D 0|  6 ,$D 0  ~{ ~g NS0fS/f]Ms^v5ugS^ S^_-NTir(vSf[ϑpeTXNNN[v Ppe [5ug5uRvpe?" n3zB   < D>?" 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AA  n3  # @y,$D 02  H >?" n3zB  < D>?" AA  n3 # 2@ny,$D 02  H >?" n3zB  < D>?" AA  n3 #  " ,$D 02  H >?" n3zB  < D>?" AAH  0޽h ? ̙3333f^___PPT10>+?KDz' = @B D5' = @BA?%,( < +O%,( < +D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*++0+  ++0+  ++0+  +  (  r  S h\`0     0d,$D 0 *4.3.1 'lSBRT؏SBRv[:_1_vk *bb   67~ ,$D 0 \]w j+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+p+0+  ++0+  +  t l  ,  (  r  S XT\`0   B l 5  ,5 ,$D 0  65 ,$ 0 ,:D O4.4 NR N*N5ug-N(WhQagN NTyir(/fg:_v'lSBRvQ-NMnO4/Mn2+v5ug9e:N(WpH=5.00vagN N [Nv'lS'`v[:_1_!k^\`7h9eS]w j (MnO4-/Mn2+) = 1.507V j (Br2/Br-) = 1.066V j (I2/I-) = 0.5355V6j bbbjbjb b b FBJJBJB                %             n3 #   ,$D 02  H >?" n3zB  < D>?" 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AA  n3  # L,$D 02  H >?" n3zB  < D>?" AA  n3 #  @,$D 02  H >?" n3zB  < D>?" AAH  0޽h ? ̙3333   6.(  r  S h3\`0   z  B ?"0,$D 0  SE0 S_ j(ck) j ()e sS\O:N'lSBR5u[v5ug5uRNpe0 sS G <0 S^ckTS E =0 sSG =0 S^YNs^ar` E <0 sSG >0 S^ckT^S(Ǐ zSS  rvxf&f&f&f&f& f & f & f & f  f  f  f  f  f & f & f  f & f & f & f  f  f  f  f  f                        H  0޽h ? ̙3333IA___PPT10!+{D' = @B DP' = @BA?%,( < +O%,( < +D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?\CB#ppt_xBCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?dCB1+#ppt_h/2BCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*5%(D' =+4 8?\CB#ppt_xBCB#ppt_xB*Y3>B ppt_x<*5D' =+4 8?dCB1+#ppt_h/2BCB#ppt_yB*Y3>B ppt_y<*5D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*5P%(D' =+4 8?\CB#ppt_xBCB#ppt_xB*Y3>B ppt_x<*5PD' =+4 8?dCB1+#ppt_h/2BCB#ppt_yB*Y3>B ppt_y<*5PD{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*Pr%(D' =+4 8?\CB#ppt_xBCB#ppt_xB*Y3>B ppt_x<*PrD' =+4 8?dCB1+#ppt_h/2BCB#ppt_yB*Y3>B ppt_y<*Pr+p+0+  ++0+  +V#  (  r  S \`0   |z +j  j+,$D 0  < ?"+j $DO4.5 Ջ$ReN NS^ (WH Sm^:N1.0010 5moldm-3nm-NۏLeveT(vQYOir(YNhQ`)0 2Mn2+ + 5Cl2 +8H2O 2MnO4- + 16H+ + 10Cl-</ bc `h `h` `         bjjbjbj Z      -  D  3 A?C   B ?" ,$ 0 FN((H+Sm^)[S^q_T_'Y S_c(H+)10-5 moldm-3e 1uNvQ[ir(GWYNhQr` R9hnceyre z_{S_ VFfn ffbbbjbjb b     B      R  H4 ?"t,$0 $ : (uhQ5ug5uR\O:N$Rnc Bcc  ~l    ,$D 0   H  ?"   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ZX (-)Zn\ZnSO4(c1) CuSO4(c2)\Cu(+) - 2Df @H@@H @H@@H@b &     fN , \    H  x B   BDԔ?", , B   BDԔ?"\ \ 6  6 D,$ 0 6(4) NNSv'lS؏SS^SN~bN*NS5u`l040Z2b n <  6p!@I,$ 0 S5u`lňnS(uV_h:y0 Vf f f b  B  6I  ,$ 0  OYCu-ZnS5u`lSh:y:N <bca(    (l    ,$D 0  <  ĉ[:gQ(W] ckgQ(WS NSZW~( )h:yveh NUSW~(|)h:y$N*NvKNvLub0(u , egR$Ny N Ty{|b N TN`nm0 XJbEff g J B  HDԔ?"xB  HDԔ?"H  0޽h ? ̙3333-%___PPT10+AdDA' = @B D' = @BA?%,( < +O%,( < +D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*Dn' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(++0+  ++0+  ++0+  +I  ph(  r  S d\   N  BP?"ON  tS(ueg~bJS5u`l5ugv'lS؏S5u[ dё^\NvQ[^vё^\vnmNY ؏ g^ё^\US(SvQ[^v^ё^\yP[(YH2/H+ O2/OH- Cl2/Cl-)0 TNyё^\ N TNvyP[(YFe3+/Fe2+ Cr2O72-/Cr3+ MnO4-/Mn2+)I{0[NT$N (W~b5uge8^YR`'`[5uSOPge(`'`5ug)YPt N"l5ug:NO Sh:y:N H+(c)|H2 (p) |Pt0`6bjbjbjbjbjbjbjbjbjbjjbjbjjbj1bjbbbjbbbjb5                        H  0޽h ? ̙3333y___PPT10Y+D=' = @B +v  jb(  r  S Q\`0   H  0Dp  ,$ 0  5u g {| W 5u [(>NO) 5u g ё^\5ug Zn2+/Zn Zn2+(c) | Zn ^ё^\5u g Cl2/Cl- Cl- (c) | Cl2(p) | Pt 'lS؏S5ug Fe3+/Fe2+ Fe3+ (c1),Fe2+ (c2) | Pt nv5ug AgCl/Ag Cl- (c) | AgCl | Agvg "f b b j b j b b b b b j b j b j b b b j b b b b b j b j  b j b b j b j b b j b b b j b b b "         )         H  0޽h ? ̙3333___PPT10+LFD8' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%slide(fromBottom)*<3<*D' =%(D' =%(DR' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%slide(fromBottom)*<3<*8D' =%(D' =%(DR' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8h%(D' =-6B%slide(fromBottom)*<3<*8hD' =%(D' =%(DR' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h%(D' =-6B%slide(fromBottom)*<3<*hD' =%(D' =%(DR' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%slide(fromBottom)*<3<*+8+0+  +Q  ~ v   (  r  S \`0     6$0C,$D 0 &1.5u`lS^v%GmN5uRREvsQ| ffnfffbB     l MM  MM,$D 06  0X MM,$D 0 * [5uRR:NEv5u`lS^ Cu2++Zn!Zn2++Cu 9hnchQid\ubqThQid\ub T^eQpe SBl_(298.15Ke) DrHm = -217.2 kJmol-1 DrGm = -212.69 kJmol-1vX0vZ>vxc(bbbb( f ( n ( f ( n ( f (% b  b   b   $ $ $ $ $b$b$b$j$f$ $j$b$j$ b $  $ b $ b ( b $ j $                 lT x #   2  HjJ?"xzB  <DjJ?"|l|lT x # x  2   HjJ?"xzB   <DjJ?"|l|H  0޽h ? ̙3333{ s ___PPT10S +P;kD ' = @B D ' = @BA?%,( < +O%,( < +D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*Dn' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<* D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<* +8+0+  +=.  ( &+ (  r  S \`0   2  0x2dy,$D0 0rGm= w'max = -QE = -nFEf&n&f&n&f&f&f&n&f&f&n&f&f&4    z g7  d,,$D0   6h( x (WS5u`l-N, 6 `b`  h   6Pg7  ^SOyRw ' sS:N5uRwe, ```f&``h`4    4   B| ?" ,$D0 4 NpRf[vSf[S^I{)n_-N S_0R N_b    6 .1M,$D0 &d N_y:N5uRRveyrW.Nernst e z,5uRR/f:_^'`(,vQ?" n3zB  < D>?" AA\@ T) *T)@ T) )T)  B- T@bNf& rT 0 # T)l  B8Ԕ rGm= -nFE f&n&f&n&f&f&4      <xI   hb4f&n&   BԔ 0 <rGm = -nFE f&n&f&n&f&n&f&f&n&4    lT  n3 # W $ ]2  H >?" n3zB  < D>?" AAtz + ]   + ] ,$D0  0A M?f?+ ] 8 M$D 0fT  n3 #   2  B >?" n3zB  < D>?" AAfT  n3 # . ] 2   B >?" n3zB ! < D>?" AAfT  n3 "# ! P' 2 # B >?" n3zB $ < D>?" AAl 9 (,$D0 g  ; 9,$D 0  6  &/f|~S(uegZP^SOyRvRϑ ,4```     6g rGmVd&l&d&l&   ' <$?"  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TQ?" h KClnm0Za  6  TDU?"* u  Hg2Cl2Z0Zckck    T[?"(   ^Hg 0Zc    TP_?"\ e  \Pt0Za  H  0޽h ? ̙3333___PPT10+D' = @B D' = @BA?%,( < +O%,( < +D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*Dn' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*++0+  ++0+  ++0+  +  p(  d  6QP,$ 0 X 9hnc Nel S)R(uhQ"l5ugbSk5ugKm_N|R_[5ugvhQ5ug5uR0@- 2f b &b - z  6HP) ,$ 0  fN+gDU_10-NRQ298.15KehQr`;m^(a=1,SRp=100kPa) NvNN'lS؏S5u[vhQ5ug5uR,h-N/f c Npe+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+p+0+  ++0+  +[4  ##`.E@&#(  l   C ,$D 0t   > ,$D 0  B/?   e 2.866       `  B>?D   e 0.401       `  B??D  e 0.3419       `  BN?w d 0       `  BlV?1w e -0.7618       `   B^?1 e -2.71       `   B`?   /V.     `h   B,s?    2 F2(g)+2e = 2F(aq) R   4     `x   B? 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